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Glycidyl methacrylate → Propylene glycol methyl ether acetate

HRID 1618844
ノート
印刷プレビュー

反応式

HRID 1618844 の反応式
[C:1]([O:6][CH:7]([O:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH3:8])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:14]([O:19][CH2:20][CH:21]1[O:23][CH2:22]1)(=[O:18])[C:15]([CH3:17])=[CH2:16].C(C(C)=O)C(C)C.N(C(C)(CC)C([O-])=O)=NC(C)(CC)C([O-])=O>CCCCCCC>[C:7]([O:9][CH:10]([CH3:11])[CH2:14][O:19][CH3:20])(=[O:6])[CH3:8].[C:1]([O:6][CH:7]([O:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH3:8])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:14]([O:19][CH2:20][CH:21]1[O:23][CH2:22]1)(=[O:18])[C:15]([CH3:17])=[CH2:16]
参加物実験手順後処理出典と根拠反応ノート

参加物

7

反応物 4

HCID 7837Glycidyl methacrylateHCID 7909Methyl Isobutyl KetoneHCID 219175032,2'-Azobis(methyl 2-methylpropanate)HCID 219599501-Butoxyethyl methacrylate

生成物 2

HCID 7946Propylene glycol methyl ether acetateHCID 866432061-n-Butoxyethyl methacrylate glycidyl methacrylate

試薬・触媒・溶媒

1
HCID 8900Heptane溶媒

実験手順

A 500 ml three-necked flask was charged with 67.1 g (0.36 mol) of 1-n-butoxyethyl methacrylate, 34.1 g (0.24 mol) of glycidyl methacrylate and 300 ml of methyl isobutyl ketone. A catalytic amount of 2,2′-azobis(methyl 2-methylpropionate) as a radical polymerization initiator was added to the mixture, and polymerization was performed in a nitrogen stream at 80° C. for six hours. The obtained reaction liquid was cooled, and poured in a large volume of heptane, thereby precipitating a polymer. The polymer crystal was collected by filtration, and dissolved in propylene glycol monomethyl ether acetate. The heptane and methyl isobutyl ketone contained in the solution were distilled off in vacuum, thereby obtaining a propylene glycol monomethyl ether acetate solution of polymer A-1 (1-n-butoxyethyl methacrylate/glycidyl methacrylate).

後処理

  1. customThe obtained reaction liquid
  2. temperaturewas cooled
  3. customprecipitating a polymer
  4. filtrationThe polymer crystal was collected by filtration
  5. dissolutiondissolved in propylene glycol monomethyl ether acetate
  6. distillationwere distilled off in vacuum

出典と根拠

ORDレコード
ord-732cc4fcff444f2f846c9ab40e5e0d26
出典データセット
uspto-grants-2014_07
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US08771907B2

反応ノート

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