Hydrazine → 2,4-Dimethylbenzohydrazide

HRID 1625576

反応式

HRID 1625576 の反応式
[CH3:1][C:2]1[CH:11]=[C:10]([CH3:12])[CH:9]=[CH:8][C:3]=1[C:4](OC)=[O:5].[NH2:13][NH2:14]>CO>[CH3:1][C:2]1[CH:11]=[C:10]([CH3:12])[CH:9]=[CH:8][C:3]=1[C:4]([NH:13][NH2:14])=[O:5]

参加物

4

反応物 2

HCID 9321HydrazineHCID 32031Methyl 2,4-dimethylbenzoate

生成物 1

HCID 48461732,4-Dimethylbenzohydrazide

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

To a solution of methyl 2,4-dimethylbenzoate (2 g, 12.2 mmol) in MeOH (10 mL) was added anhydrous hydrazine (1.95 mL, 61 mmol) and the mixture was heated under reflux for 40 hours. Then the mixture was evaporated and dried under vacuum to give 2,4-dimethylbenzohydrazide as a white solid (2 g, 100%; MS (M+H, 165).

後処理

  1. temperaturethe mixture was heated
  2. temperatureunder reflux for 40 hours
  3. customThen the mixture was evaporated
  4. customdried under vacuum

出典と根拠

ORDレコード
ord-0c7a3d9d10ba4e2b964212cfbbb97f70
出典データセット
uspto-grants-2014_07
特許番号
US08784782B2

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