Aniline → N-(3-Methoxybenzylidene)aniline

HRID 1632608

反応式

HRID 1632608 の反応式
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:8]=[CH:9][CH:10]=1)[CH:6]=O.[NH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>CCOCC>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:8]=[CH:9][CH:10]=1)[CH:6]=[N:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1

参加物

4

反応物 2

HCID 6115AnilineHCID 115693-Methoxybenzaldehyde

生成物 1

HCID 555084N-(3-Methoxybenzylidene)aniline

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

A solution of 85.4 gm. of 3-methoxybenzaldehyde, 58.7 gm. of aniline, and 185 gm. of 3A molecular sieves in 700 ml. of anhydrous ether was refluxed for 16 hours. The ether was dried (Na2SO4), filtered, and concentrated in vacuo to an oil which upon distillation provided 93.2 gm of oil. b.p. 141°-143°/0.5 Torr.

後処理

  1. dry with materialThe ether was dried (Na2SO4)
  2. filtrationfiltered
  3. concentrationconcentrated in vacuo to an oil which upon distillation

出典と根拠

ORDレコード
ord-312d2c2fdff149489cd828aa97a97e7e
出典データセット
uspto-grants-1984_10
特許番号
US04476311

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