Acrylamide → t-Butylacrylate Acrylamide

HRID 1636454

反応式

HRID 1636454 の反応式
[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[C:10]([NH2:14])(=[O:13])[CH:11]=[CH2:12]>C(O)(C)C>[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[C:10]([NH2:14])(=[O:13])[CH:11]=[CH2:12]

参加物

4

反応物 2

HCID 6579AcrylamideHCID 15458tert-Butyl acrylate

生成物 1

HCID 86584091t-Butylacrylate Acrylamide

試薬・触媒・溶媒 1

HCID 3776Isopropanol溶媒

反応条件

温度
75 °C

実験手順

To a 500 mL round-bottom, three-neck flask fitted with a thermocouple, reflux condenser, and septum was added 150 mL of isopropanol followed by 16.13 g of a 50% aqueous solution of 2-trimethylammoniumethylacrylate chloride, 8.06 g of t-butylacrylate, and 8.06 g of acrylamide. The solution was purged with nitrogen for 1 hour and 0.5 g AIBN was added. The mixture was purged for ~ 15 minutes until all of the AIBN dissolved. The solution was heated to 75° C. under nitrogen for 16 hours.

後処理

  1. customTo a 500 mL round-bottom, three-neck flask fitted with a thermocouple
  2. temperaturereflux condenser
  3. customThe solution was purged with nitrogen for 1 hour
  4. addition0.5 g AIBN was added
  5. customThe mixture was purged for ~ 15 minutes until all of the AIBN
  6. dissolutiondissolved

出典と根拠

ORDレコード
ord-e2cf5919043340139e422b97301a4def
出典データセット
uspto-grants-2000_03
特許番号
US06034129

関連ノート

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