Hydrochloric Acid → HCID 13849834、化合物
反応式
[Cl:1][C:2]([Cl:4])=[CH2:3].Cl[C:6]([CH3:13])([CH2:9][CH2:10][CH2:11][CH3:12])[CH2:7][CH3:8].Cl>[Fe](Cl)(Cl)Cl>[Cl:1][C:2]([Cl:4])=[CH:3][C:6]([CH2:7][CH3:8])([CH3:13])[CH2:9][CH2:10][CH2:11][CH3:12]参加物
5
反応条件
- 温度
- 30 °C
実験手順
1,235 g (12.7 moles) of 1,1-dichloroethene and 630 g (4.23 moles) of 3-chloro-3-methylheptane are taken at 20° C. 85 g of anhydrous iron(III) chloride are added in portions, while cooling. The mixture is then subsequently stirred at 30° C. for 2 hours. It is poured onto ice and dilute aqueous hydrochloric acid. The organic phase is separated off, dried and subjected to fractional distillation. 627 g (71% of theory) of 1,1-dichloro-3-ethyl-3-methyl-hept-1-ene are isolated at boiling point6.1 50°-60° C.
後処理
- customare taken at 20° C
- temperaturewhile cooling
- customThe organic phase is separated off
- customdried
- distillationsubjected to fractional distillation
出典と根拠
- ORDレコード
- ord-9a044a6479a2485b8c806df96604a23c
- 出典データセット
- uspto-grants-1989_11
- 特許番号
- US04878939
反応ノート
読み込み中…