3-Isopropoxy-4-nitrotoluene → 4-Methyl-2-(propan-2-yloxy)aniline

HRID 1639116ノート

反応式

HRID 1639116 の反応式
[CH3:1][C:2]1[CH:3]=[CH:4][C:5]([N+:12]([O-])=O)=[C:6]([O:8][CH:9]([CH3:11])[CH3:10])[CH:7]=1.[H][H]>CO.[Pd]>[CH3:1][C:2]1[CH:3]=[CH:4][C:5]([NH2:12])=[C:6]([O:8][CH:9]([CH3:11])[CH3:10])[CH:7]=1

参加物

5

反応物 2

HCID 5927313-Isopropoxy-4-nitrotolueneHCID 178418361HCID 178418361、化合物2 回

生成物 1

HCID 150681144-Methyl-2-(propan-2-yloxy)aniline

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 887Methanol溶媒

実験手順

5-Methyl-1-(1-methylethoxy)-2-nitrobenzene, 17.7 g (91 mmol), is dissolved in methanol, palladium on charcoal is added and the mixture is exposed to hydrogen gas until the required amount of hydrogen is absorbed. The mixture is worked up in the usual manner to give 15 g of 4-methyl-2-(1-methylethoxy)benzenamine.

後処理

  1. customis absorbed

出典と根拠

ORDレコード
ord-3e627e157205460095844073242a2bc9
出典データセット
uspto-grants-1989_11
特許番号
US04882357

反応ノート

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