N,N-bis(1H-benzimidazol-2-ylmethyl)amine chromium (III) chloride hexafluoroantimonate tetrahydrofuran → N,N-bis(1H-benzimidazol-2-ylmethyl)-N-methylamine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

HRID 1645214ノート

反応式

HRID 1645214 の反応式
[O:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][Sb-:7]([F:12])([F:11])([F:10])([F:9])[F:8].[Cl-:13].[Cr+3:14].N1C2C=CC=CC=2N=C1CNCC1NC2C=CC=CC=2N=1.[Cl-].[Cr+3].[NH:38]1[C:42]2[CH:43]=[CH:44][CH:45]=[CH:46][C:41]=2[N:40]=[C:39]1[CH2:47][N:48]([CH2:55][C:56]1[NH:60][C:59]2[CH:61]=[CH:62][CH:63]=[CH:64][C:58]=2[N:57]=1)[CH2:49]CCCCC.[Cl-].[Cl-]>F[Sb-](F)(F)(F)(F)F.[Ag+].C1COCC1>[O:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][Sb-:7]([F:12])([F:11])([F:10])([F:9])[F:8].[Cl-:13].[Cr+3:14].[NH:38]1[C:42]2[CH:43]=[CH:44][CH:45]=[CH:46][C:41]=2[N:40]=[C:39]1[CH2:47][N:48]([CH2:55][C:56]1[NH:57][C:58]2[CH:64]=[CH:63][CH:62]=[CH:61][C:59]=2[N:60]=1)[CH3:49]

参加物

5

反応物 2

HCID 86638469N,N-bis(1H-benzimidazol-2-ylmethyl)amine chromium (III) chloride hexafluoroantimonate tetrahydrofuranHCID 86638471N,N-bis(1H-benzimidazol-2-ylmethyl)-N-hexylamine chromium (III) chloride

生成物 1

HCID 86638468N,N-bis(1H-benzimidazol-2-ylmethyl)-N-methylamine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

試薬・触媒・溶媒 2

HCID 16687962Silver hexafluoroantimonate触媒HCID 8028Tetrahydrofuran溶媒

実験手順

4b was synthesised by an analogous procedure to that described for 4a using silver hexafluoroantimonate (0.661 g, 1.92 mmol) and complex 3e (1 g, 1.92 mmol). Yield 1.32 g, 87%. +FAB-MS: (m/e): 483 ([M]+), 467 ([M-Me]+), 449 ([M-Cl]), 361 ([M-Cr, Cl, THF). −FAB-MS: (m/z): 235 ([M]−).

出典と根拠

ORDレコード
ord-6a647d4d20a84b88be9115cbd47872ea
出典データセット
uspto-grants-2012_02
特許番号
US08124698B2

反応ノート

読み込み中…