Benzyl Chloride → 1,1-Diphenylethane

HRID 1651852ノート

反応式

HRID 1651852 の反応式
[CH2:1](Cl)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1>[Fe].Cl[Cu].O>[C:2]1([CH:1]([C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[CH3:1])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

5

反応物 1

HCID 7503Benzyl Chloride

生成物 1

HCID 119181,1-Diphenylethane収率 71.4%

試薬・触媒・溶媒 3

HCID 23925Iron触媒HCID 62652Cuprous chloride触媒HCID 962Water溶媒

実験手順

The procedure of Example I was repeated except that the reaction mass contained 150 ml water, 5.6 g iron (99.9+% pure), 0.2 g CuCl (99.9% pure), and 25.4 g benzyl chloride. The reaction period was for 3 hr. 13.0 g of crude diphenylethane product was obtained. This represents a 71.4% yield.

後処理

  1. customThe reaction period

出典と根拠

ORDレコード
ord-71e142610d554d66ac361faaf2269a06
出典データセット
uspto-grants-1990_05
特許番号
US04929785

反応ノート

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