Methyl iodide → methyl N,N'-diphenylcarbamimidothioate hydroiodide

HRID 1657576ノート

反応式

HRID 1657576 の反応式
[CH:1]1[CH:6]=[CH:5][C:4]([NH:7][C:8]([NH:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[S:9])=[CH:3][CH:2]=1.[CH3:17][I:18]>C(O)C>[IH:18].[CH3:17][S:9][C:8](=[N:7][C:4]1[CH:3]=[CH:2][CH:1]=[CH:6][CH:5]=1)[NH:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

参加物

4

反応物 2

HCID 6328Methyl iodideHCID 700999Diphenylthiourea

生成物 1

HCID 2801577methyl N,N'-diphenylcarbamimidothioate hydroiodide

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

A mixture of 22.8 gm. (0.1 mole) of thiocarbanilide and 17 gm. (0.12 mole) of methyl iodide in 400 ml. of ethanol is heated at reflux for 6 hours. The solvent is evaporated and residue is crystallized from ethyl acetate; 29 gm. (78%), m.p. 155°-156°.

後処理

  1. additionA mixture of 22.8 gm
  2. temperatureat reflux for 6 hours
  3. customThe solvent is evaporated
  4. customresidue is crystallized from ethyl acetate

出典と根拠

ORDレコード
ord-513311e90a254b1da62f90c61999eb62
出典データセット
uspto-grants-1976_06
特許番号
US03961056

反応ノート

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