反応式
[Na].[N+:2]([CH:5]1[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]1)([O-:4])=[O:3].Br[C:12]([N+:15]([O-:17])=[O:16])([CH3:14])[CH3:13]>>[CH3:13][C:12]([C:5]1([N+:2]([O-:4])=[O:3])[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]1)([N+:15]([O-:17])=[O:16])[CH3:14]参加物
4
実験手順
Seigle and Hass, J. Org. Chem., 5, 100(1940), reported the reaction of the sodium salt of nitrocyclohexane with 2-bromo-2-nitropropane to give 1-(1-methyl-1-nitroethyl)-1-nitrocyclohexane. From the sodium salt of 2-nitropropane and 2-bromo-2-nitropropane they obtained 2,3-dimethyl-2,3-dinitrobutane. Other compounds prepared in like manner were 2,3-dimethyl-2,3-dinitropentane and 3,4-dimethyl-3,4-dinitrohexane. The method is limited to the preparation of α,β-dinitro compounds, and only low yields were reported.
出典と根拠
- ORDレコード
- ord-63d9a9c899aa40c5b5559af6ed79c6f1
- 出典データセット
- uspto-grants-1976_06
- 特許番号
- US03962053
関連ノート
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