Hydrochloric Acid → HCID 12575251、化合物

反応式

S(Cl)(Cl)=O.[C:5]([OH:15])(=O)/[CH:6]=[CH:7]/[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[ClH:16]>>[C:5]([Cl:16])(=[O:15])/[CH:6]=[CH:7]/[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

参加物

反応物 3

HCID 313Hydrochloric Acid

HCID 24386Thionyl Chloride

HCID 5312586(E)-2-Nonenoic Acid

生成物 1

HCID 12575251HCID 12575251、化合物収率 91%

反応条件

温度: 130 °C

実験手順

Thionyl chloride (131 g, 1.1 mole) is added to trans-2-nonenoic acid (156 g, 1.0 mole). Reaction occurs immediately with the evolution of HCl and SO2. After the initial reaction subsides, the mixture is heated slowly to 130°C. The dark mixture is vacuum distilled to yield trans-2-nonenoyl chloride, b.p. 90°C/2 mm, 155 g, 91% yield.

後処理

customReaction
customAfter the initial reaction subsides
distillationdistilled

出典と根拠

ORDレコード: ord-571b4d0b56cf47a3b7999232a4246a05
出典データセット: uspto-grants-1976_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US03962321

反応ノート

読み込み中…