CID 21884946 → Di-n-dodecyl 5-tert.-octyl-2,3-dimethyl-4-hydroxybenzylphosphonate

HRID 1658036ノート

反応式

HRID 1658036 の反応式
[C:1]([C:9]1[C:14]([OH:15])=[C:13]([CH3:16])[C:12]([CH3:17])=[C:11]([CH2:18]N(C)C)[CH:10]=1)([CH2:4][C:5]([CH3:8])([CH3:7])[CH3:6])([CH3:3])[CH3:2].[P:22]([O-:49])([O:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH3:48])[O:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35]>C(#N)C>[C:1]([C:9]1[C:14]([OH:15])=[C:13]([CH3:16])[C:12]([CH3:17])=[C:11]([CH:10]=1)[CH2:18][P:22](=[O:49])([O:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH3:48])[O:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35])([CH2:4][C:5]([CH3:8])([CH3:7])[CH3:6])([CH3:3])[CH3:2]

参加物

4

反応物 2

HCID 21884946CID 21884946HCID 867335566-tert.-Octyl-2,3-dimethyl-4-(dimethylaminomethyl)phenol

生成物 1

HCID 86733555Di-n-dodecyl 5-tert.-octyl-2,3-dimethyl-4-hydroxybenzylphosphonate

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

This compound was made in a similar manner as Example 5 by reacting 6-tert.-octyl-2,3-dimethyl-4-(dimethylaminomethyl)phenol (Example 2) with di-n-dodecyl phosphite. After trituration with acetonitrile, the desired compound is obtained as white crystals melting at 36° to 40°C (Compound 7).

出典と根拠

ORDレコード
ord-417426fc91f8494f9770295ca9a019e8
出典データセット
uspto-grants-1976_06
特許番号
US03962377

反応ノート

読み込み中…