Butylamine → HCID 178514954、化合物

HRID 1658850ノート

反応式

HRID 1658850 の反応式
[N+:1]([C:4]1[CH:17]=[CH:16][CH:15]=[C:14]2[C:5]=1[C:6](=[O:19])[CH:7]1[CH:12]([C:13]2=[O:18])[CH2:11][CH:10]=[CH:9][CH2:8]1)([O-])=[O:2].C(N)CCC>C1(C)C=CC=CC=1>[OH:2][NH:1][C:4]1[C:5]2[C:6](=[O:19])[C:7]3[C:12](=[CH:11][CH:10]=[CH:9][CH:8]=3)[C:13](=[O:18])[C:14]=2[CH:15]=[CH:16][CH:17]=1

参加物

4

反応物 2

HCID 8007ButylamineHCID 108689405-Nitro-1,4,4a,9a-tetrahydroanthraquinone

生成物 1

HCID 178514954HCID 178514954、化合物

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
70 °C

実験手順

A mixture of 5.0 parts of 5-nitro-1,4,4a,9a-tetrahydroanthraquinone with 80 parts of toluene and 1.0 part of n-butylamine was stirred at 70°C for 2 hours. The mixture was then distilled under a reduced pressure of 100 mm Hg to remove toluene, washed with 50 parts of methanol and dried under reduced pressure to obtain 4.4 parts of 1-hydroxylaminoanthraquinone.

後処理

  1. distillationThe mixture was then distilled under a reduced pressure of 100 mm Hg
  2. customto remove toluene
  3. washwashed with 50 parts of methanol
  4. customdried under reduced pressure

出典と根拠

ORDレコード
ord-b3584de3cd3b4e89ac040e3cef6b4bc3
出典データセット
uspto-grants-1976_06
特許番号
US03966775

反応ノート

読み込み中…