Styrene → Butyl prop-2-enoate;styrene

反応式

CC(=N)C.C(OCCO)CCC.[CH2:13]=[CH:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[C:21]([O:25][CH2:26][CH2:27][CH2:28][CH3:29])(=[O:24])[CH:22]=[CH2:23]>>[CH2:13]=[CH:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[C:21]([O:25][CH2:26][CH2:27][CH2:28][CH3:29])(=[O:24])[CH:22]=[CH2:23]

参加物

反応物 4

HCID 7501Styrene

HCID 81332-Butoxyethanol

HCID 8846Butyl Acrylate

HCID 1423042-Propanimine

生成物 1

HCID 168422Butyl prop-2-enoate;styrene

実験手順

The procedure described in part (a) of example 21 is repeated using 1076 g of 2-butoxyethanol, 1780 g of styrene, 730 g of butyl acrylate (BA), an initial charge of 179.2 g of 75% t-BP (in mineral spirits) and a final charge of 17.9 g thereof, a monomer feed time of 4.5 hours and a polymerization temperature of 150° C.