N-vinyl-2-pyrrolidone → HCID 86738171、化合物
反応式
[CH2:1]([N:4]([CH2:13][CH:14]=[CH2:15])[CH:5]=[CH:6][CH:7]=[C:8]([C:11]#[N:12])[C:9]#[N:10])[CH:2]=[CH2:3].[CH:16]([N:18]1[CH2:22][CH2:21][CH2:20][C:19]1=[O:23])=[CH2:17]>CN1CCCC1=O>[CH:16]([N:18]1[CH2:22][CH2:21][CH2:20][C:19]1=[O:23])=[CH2:17].[CH2:1]([N:4]([CH:5]=[CH:6][CH:7]=[C:8]([C:9]#[N:10])[C:11]#[N:12])[CH2:13][CH:14]=[CH2:15])[CH:2]=[CH2:3]参加物
4
反応条件
- 温度
- 85 °C
実験手順
25 g of intermediate (A) and 25 g of vinylpyrrolidone were dissolved in 100 ml of N-methylpyrrolidone and added with 2.5 g of AZBN. The mixture was then heated to reflux at 85° C. for 6 hours in a flask provided with a stirrer and reflux condenser, then it was cooled, precipitated in ether and dried at 50° C. The yield was 15.7 g of a product soluble in 40:60 water-ethanol, containing about 44% w/w of aminoallylidenmalononitrile moieties.