4,4-Diethylcyclohex-2-en-1-one → 4,4-Diethylcyclohexan-1-one
反応式
[CH2:1]([C:3]1([CH2:10][CH3:11])[CH2:8][CH2:7][C:6](=[O:9])[CH:5]=[CH:4]1)[CH3:2]>CC(=O)OCC.[Pd]>[CH2:10]([C:3]1([CH2:1][CH3:2])[CH2:8][CH2:7][C:6](=[O:9])[CH2:5][CH2:4]1)[CH3:11]参加物
4
実験手順
A solution of 4,4-diethyl-cyclohex-2-enone (10.7 g, 70.5 mmol) in EA (400 mL) is treated with Pd/C (1.0 g, 10% Pd). The suspension is stirred at rt for 24 h under 1 bar of H2. The mixture is filtered, and the filtrate is evaporated to give 4,4-diethyl-cyclohexanone (11.7 g) as a colourless solid; 1H NMR (CD3OD): δ 2.32 (t, J=7.0 Hz, 4H), 1.66 (t, J=7.0 Hz, 4H), 1.48 (q, J=7.6 Hz, 4H), 0.88 (t, J=7.6 Hz, 6H).
後処理
- filtrationThe mixture is filtered
- customthe filtrate is evaporated
出典と根拠
- ORDレコード
- ord-15cc66cb371340c2ad991a7a144c8428
- 出典データセット
- uspto-grants-2011_10
- 特許番号
- US08039644B2
反応ノート
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