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tert-Butyl methacrylate → t-Butyl methacrylate 4-vinylquinoline 4-acetoxystyrene

HRID 1668276
ノート
印刷プレビュー

反応式

HRID 1668276 の反応式
[C:1]([O:4][C:5]1[CH:12]=[CH:11][C:8]([CH:9]=[CH2:10])=[CH:7][CH:6]=1)(=[O:3])[CH3:2].[C:13]([O:18][C:19]([CH3:22])([CH3:21])[CH3:20])(=[O:17])[C:14]([CH3:16])=[CH2:15].[CH:23]([C:25]1[C:34]2[C:29](=[CH:30][CH:31]=[CH:32][CH:33]=2)[N:28]=[CH:27][CH:26]=1)=[CH2:24].N(C(C)(C)C(OC)=O)=NC(C)(C)C(OC)=O>C1(=O)CCCCC1.CCCCCC>[C:13]([O:18][C:19]([CH3:22])([CH3:21])[CH3:20])(=[O:17])[C:14]([CH3:16])=[CH2:15].[CH:23]([C:25]1[C:34]2[C:29](=[CH:30][CH:31]=[CH:32][CH:33]=2)[N:28]=[CH:27][CH:26]=1)=[CH2:24].[C:1]([O:4][C:5]1[CH:12]=[CH:11][C:8]([CH:9]=[CH2:10])=[CH:7][CH:6]=1)(=[O:3])[CH3:2]
参加物実験手順後処理出典と根拠反応ノート

参加物

7

反応物 4

HCID 11448tert-Butyl methacrylateHCID 757631,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)HCID 758214-Ethenylphenyl acetateHCID 133195774-Ethenylquinoline

生成物 1

HCID 86629094t-Butyl methacrylate 4-vinylquinoline 4-acetoxystyrene収率 299.6%

試薬・触媒・溶媒 2

HCID 7967
Cyclohexanone
溶媒
2 回
HCID 8058Hexane溶媒

実験手順

4-Acetoxystyrene (29.19 g) (0.18 mol), 12.80 g (0.09 mol) of t-butyl methacrylate, 4.66 g (0.03 mol) of 4-vinylquinoline, and 3.45 g (0.015 mol) of polymerization initiator V-601 (manufactured by Wako Pure Chemical Industries) are dissolved in 148.99 g of cyclohexanone. Cyclohexanone (37.25 g) is put in a reaction vessel and the above solution is dropped into the reaction system at 80° C. over 6 hours under nitrogen gas atmosphere. After dropping, the reaction solution is stirred while heating for 2 hours, and then allowed to cool to room temperature. The solution is dropped into 2.5 liters of hexane to thereby precipitate and filter the polymer. The solid filtered is roughly washed with 500 ml of hexane and dried under reduced pressure to obtain 41.30 g of t-butyl methacrylate/4-vinylquinoline/4-acetoxystyrene copolymer.

後処理

  1. additionthe above solution is dropped into the reaction system at 80° C. over 6 hours under nitrogen gas atmosphere
  2. temperaturewhile heating for 2 hours
  3. customto thereby precipitate
  4. filtrationfilter the polymer
  5. filtrationThe solid filtered
  6. washis roughly washed with 500 ml of hexane
  7. customdried under reduced pressure

出典と根拠

ORDレコード
ord-ff772c5ce1d44ddb8c9cd9f6dbc6d075
出典データセット
uspto-grants-2011_08
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US07989137B2

反応ノート

読み込み中…

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