1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate) (HCID 75763)

名称と識別子

優先名称: 1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)
IUPAC: methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate
現地名: 2,2'-アゾビス(イソ酪酸メチル)
英語名: Dimethyl 2,2'-azobis(2-methylpropionate)
分子式: C10H18N2O4
分子量: 230.26

名称と別名

2589-57-31,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis[2-methylpropanoate]RefChem:196631Dimethyl 2,2'-azobis(2-methylpropionate)Dimethyl 2,2'-(diazene-1,2-diyl)bis(2-methylpropanoate)methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoatedimethyl 2,2'-azobisisobutyrateG88X6P053Wdimethyl 2,2-azobis(2-methylpropionate)Dimethyl-2,2'-azobis(2-methylpropionate)2,2-Azobisisobutyric acid dimethyl ester

名称をさらに表示

2,2'-アゾビス(2-メチルプロパン酸メチル)2,2'-アゾビス(2-メチルプロパン酸)ジメチル2,2'-アゾビス(2-メチルプロピオン酸)ジメチル2,2'-アゾビス(2-メチルプロピオン酸メチル)2,2'-アゾビス(イソ酪酸メチル)2,2'-アゾビスイソ酪酸ジメチルジメチル 2，2’アゾビス（2メチルプロピオネ-ト）ジメチル＝2，2’-（ジアゼン-1，2-ジイル）ビス（2-メチルプロパノアート）2,2'-アゾビス(イソ酪酸)ジメチル2,2′-アゾビス(イソ酪酸メチル)2,2′-アゾビスイソ酪酸ジメチル2,2′-アゾビス(2-メチルプロパン酸メチル)2,2′-アゾビス(2-メチルプロパン酸)ジメチル2,2,5,5-テトラメチル-3,4-ジアザ-3-ヘキセン二酸ジメチル2,2′-アゾビス(2-メチルプロピオン酸メチル)2,2′-アゾビス(2-メチルプロピオン酸)ジメチルメチル 2-[2-(1-メトキシ-2-メチル-1-オキソプロパン-2-イル)ジアゼン-1-イル]-2-メチルプロパノアート2,2′-(ジアゼン-1,2-ジイル)ビス(2-メチルプロパン酸メチル)1,2-ビス(1,1-ジメチル-2-オキソ-2-メトキシエチル)ジアゼンAIBMEV-601MAIBDYPR0396AIBME V601C10H18N2O4dimethyl 2,2'2-methylpropionateDimethyl 2,2'-Azobis-azobis(2-methylpropionate)

MFCD00085253Propanoic acid, 2,2'-(1,2-diazenediyl)bis(2-methyl-, 1,1'-dimethyl esterEINECS 219-976-6UNII-G88X6P053WAIBME cpddimethyl azodiisobutyratedimethyl 2,2'-azobis(2-methylpropanoate)dimethyl azobisisobutyrate

データベース識別子

CAS: 2589-57-3
PubChem CID: 75763
DTXSID: DTXSID701031497
UNII: G88X6P053W
EC Number: 219-976-6
Nikkaji: J117.182H

物性

構造計算による物性

XLogP: 1.6
極性表面積: 77.3 Å²
水素結合供与体数: 0
水素結合受容体数: 6
回転可能結合数: 6
重原子数: 16
形式電荷: 0
複雑度: 278

実験および物理化学的性質

Physical DescriptionDry Powder

物理化学的性質

融点: 22 · 22-28°C
沸点: 248.3 · 248.3±25.0 °C(Predicted)
比重(密度): 1.06 · 1.06±0.1 g/cm3(Predicted)
蒸気圧: 2.85 Pa · 2.85Pa at 20℃
貯蔵温度: 2 · Storage temp. 2-8°C
水溶解度: 不溶性
InChI: InChI=1S/C10H18N2O4/c1-9(2,7(13)15-5)11-12-10(3,4)8(14)16-6/h1-6H3
InChIKey: ZQMHJBXHRFJKOT-UHFFFAOYSA-N
SMILES: N(C(C)(C)C(OC)=O)=NC(C)(C)C(OC)=O
LogP: 2.47 at · 2.47 at 25℃
CAS データベース: 2589 · 2589-57-3(CAS DataBase Reference)

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H242 (100%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]

P210, P234, P235, P240, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P304+P340, P305+P351+P338, P317, P330, P337+P317, P370+P378, P391, P403, P410, P411, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 112 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 3 件

Propanoic acid, 2,2'-(1,2-diazenediyl)bis[2-methyl-, 1,1'-dimethyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Propanoic acid, 2,2'-(1,2-diazenediyl)bis[2-methyl-, 1,1'-dimethyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 30-08-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/28213

Hazard Classes and CategoriesSelf-react. D (100%)

安全データ

tsca: TSCA listed
hs_code: 29270000
化審法: (2)-1243
消防法: 危-5-II

化学と産業

用途と製造

U.S. Production2023: 4,850 lb

Industry UsesPolymerization promoter

General Manufacturing Information · 2 件

Plastics Material and Resin Manufacturing

Propanoic acid, 2,2'-(1,2-diazenediyl)bis[2-methyl-, 1,1'-dimethyl ester: ACTIVE

応用分野 · 2 件

用途重合開始剤。

使用Dimethyl 2,2'-azobis(2-methylpropionate) is a nitrile-free, oil-soluble azo polymerization initiator with polymerization activity similar to AIBN. However, it has fewer toxic by-products than AIBN, is safer and can be used as an alternative to AIBN. In addition, the highly volatile decomposition products can be removed during the polymer production process, and the polymer after polymerization is highly transparent, so it is expected to be used in semiconductors and liquid crystal displays(LCDs).