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Toluene → tert-butyl 2,4-dimethoxybenzyl((S)-3-((R)-4-benzyl-2-oxooxazolidin-3-yl)-2-(4-chlorophenyl)-3-oxopropyl)carbamate

HRID 1675865
ノート
印刷プレビュー

反応式

HRID 1675865 の反応式
[CH2:1]([C@@H:8]1[CH2:12][O:11][C:10](=[O:13])[N:9]1[C:14](=[O:23])[CH2:15][C:16]1[CH:21]=[CH:20][C:19]([Cl:22])=[CH:18][CH:17]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C1(C)C=CC=CC=1.CCN(C(C)C)C(C)C.[CH3:40][O:41][C:42]1[CH:59]=[C:58]([O:60][CH3:61])[CH:57]=[CH:56][C:43]=1[CH2:44][N:45]([CH2:53]OC)[C:46](=[O:52])[O:47][C:48]([CH3:51])([CH3:50])[CH3:49]>C(Cl)Cl.Cl[Ti](Cl)(Cl)Cl>[CH2:1]([C@@H:8]1[CH2:12][O:11][C:10](=[O:13])[N:9]1[C:14](=[O:23])[C@@H:15]([C:16]1[CH:17]=[CH:18][C:19]([Cl:22])=[CH:20][CH:21]=1)[CH2:53][N:45]([CH2:44][C:43]1[CH:56]=[CH:57][C:58]([O:60][CH3:61])=[CH:59][C:42]=1[O:41][CH3:40])[C:46](=[O:52])[O:47][C:48]([CH3:51])([CH3:50])[CH3:49])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

7

反応物 4

HCID 1140TolueneHCID 81531DiisopropylethylamineHCID 15421330(R)-4-benzyl-3-(2-(4-chlorophenyl)acetyl)oxazolidin-2-oneHCID 66618166Tert-butyl 2,4-dimethoxybenzyl(methoxymethyl)carbamate

生成物 1

HCID 66618472tert-butyl 2,4-dimethoxybenzyl((S)-3-((R)-4-benzyl-2-oxooxazolidin-3-yl)-2-(4-chlorophenyl)-3-oxopropyl)carbamate収率 73.5%

試薬・触媒・溶媒 2

HCID 24193Titanium Tetrachloride触媒HCID 6344Dichloromethane溶媒2 回

反応条件

温度
-78 °C

実験手順

(R)-4-Benzyl-3-(2-(4-chlorophenyl)acetyl)oxazolidin-2-one (3.00 g, 9.10 mmol) was dissolved in DCM (91 mL) and cooled to −78° C. A 1M toluene solution of TiCl4 (11.4 mL, 11.4 mmol) was added to the solution followed by DIEA (1.66 mL, 9.55 mmol) to afford a dark purple reaction. This was stirred for 15 minutes, and then tert-butyl 2,4-dimethoxybenzyl(methoxymethyl)carbamate (3.40 g, 10.9 mmol) was added dropwise as a solution in DCM (10 mL). The reaction was allowed to stir for 15 minutes at −78° C., and then allowed to warm to −18° C. in a brine-ice bath for one hour. This reaction was allowed to warm slowly to 0° C. over a 2.5 hour period and then quenched with the addition of saturated NH4Cl solution (100 mL). The layers were separated, and the organic portion was extracted once with DCM. The combined organic portions were dried over MgSO4, filtered, and concentrated in vacuo to afford a yellow oil. The residue was purified by chromatography (silica gel eluted with 4:1 hexanes:ethyl acetate) to afford the pure material as a colorless oil, tert-butyl (S)-3-((R)-4-benzyl-2-oxooxazolidin-3-yl)-2-(4-chlorophenyl)-3-oxopropyl(2,4-dimethoxybenzyl)carbamate (4.07 g, 73.5% yield). tert-Butyl (S)-3-((R)-4-benzyl-2-oxooxazolidin-3-yl)-2-(4-chlorophenyl)-3-oxopropyl(2,4-dimethoxybenzyl)carbamate (680 mg, 1.12 mmol) was dissolved in DCM (10.6 mL) and water (560 uL; 19:1 DCM:water) at ambient temperature. The solution was treated with DDQ (380 mg, 1.67 mmol), and the reaction was allowed to stir for one day to afford reaction completion by TLC and LCMS analysis. The reaction was diluted with DCM and washed twice with half saturated NaHCO3 solution. The organic portion was dried over MgSO4, filtered, and concentrated in vacuo to afford a yellow-orange oil. The residue was purified by chromatography (silica gel eluted with 9:1 hexanes:ethyl acetate) to afford a mixture of the aldehyde by-product and tert-butyl (S)-3-((R)-4-benzyl-2-oxooxazolidin-3-yl)-2-(4-chlorophenyl)-3-oxopropylcarbamate (not separable) as a pale-yellow oil (729 mg combined mass). LC/MS (APCI+) m/z 359.1 [M-BOC+H]+.

後処理

  1. customto afford
  2. customa dark purple reaction
  3. stirringto stir for 15 minutes at −78° C.
  4. temperatureto warm to −18° C. in a brine-ice bath for one hour
  5. temperatureto warm slowly to 0° C. over a 2.5 hour period
  6. customquenched with the addition of saturated NH4Cl solution (100 mL)
  7. customThe layers were separated
  8. extractionthe organic portion was extracted once with DCM
  9. dry with materialThe combined organic portions were dried over MgSO4
  10. filtrationfiltered
  11. concentrationconcentrated in vacuo
  12. customto afford a yellow oil
  13. customThe residue was purified by chromatography (silica gel eluted with 4:1 hexanes:ethyl acetate)

出典と根拠

ORDレコード
ord-5a4d089ab3634b12839b50bada739e49
出典データセット
uspto-grants-2011_08
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US08003651B2

反応ノート

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