Kaliumbenzylat → HCID 57287670、化合物

HRID 1680166ノート

反応式

HRID 1680166 の反応式
[CH3:1][O:2][C:3](=[O:19])[CH2:4][C:5]1[C:9]([NH:10][C:11]2[C:16]([Cl:17])=[CH:15][CH:14]=[CH:13][C:12]=2[Cl:18])=[CH:8][S:7][CH:6]=1.C([O-])[C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1.[K+]>C(O)C1C=CC=CC=1>[CH2:1]([O:2][C:3](=[O:19])[CH2:4][C:5]1[C:9]([NH:10][C:11]2[C:16]([Cl:17])=[CH:15][CH:14]=[CH:13][C:12]=2[Cl:18])=[CH:8][S:7][CH:6]=1)[C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1

参加物

4

反応物 2

HCID 23672811KaliumbenzylatHCID 571452364-(2,6-Dichloroanilino)-3-thiophenacetic acid methyl ester

生成物 1

HCID 57287670HCID 57287670、化合物

試薬・触媒・溶媒 1

HCID 244Benzyl Alcohol溶媒

実験手順

316 mg (1 mmole) of 4-(2,6-dichloroanilino)-3-thiophenacetic acid methyl ester are introduced into a solution of 10 mg of potassium benzyl alcoholate in 20 ml of benzyl alcohol. The mixture is stirred at room temperature for 2 hours, excess alcohol is distilled off in vacuo and 4-(2,6-dichloroanilino)-3-thiophenacetic acid benzyl ester is obtained as the residue.

後処理

  1. distillationexcess alcohol is distilled off in vacuo

出典と根拠

ORDレコード
ord-d9430393610040e599bf62f2ac339da7
出典データセット
uspto-grants-1981_06
特許番号
US04272507

反応ノート

読み込み中…