Methane → HCID 131712825、化合物

HRID 1702834

反応式

HRID 1702834 の反応式
[Cl:1][C:2]1[C:11]([CH3:12])=[N:10][C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[N:3]=1.C.[NH2:14][C:15]([NH2:17])=[S:16]>CC(C)=O>[ClH:1].[CH3:12][C:11]1[C:2]([S:16][C:15](=[NH:14])[NH2:17])=[N:3][C:4]2[C:9]([N:10]=1)=[CH:8][CH:7]=[CH:6][CH:5]=2

参加物

5

反応物 3

HCID 297MethaneHCID 2362762-Chloro-3-methylquinoxalineHCID 2723790Thiourea

生成物 1

HCID 131712825HCID 131712825、化合物

試薬・触媒・溶媒 1

HCID 180Acetone溶媒2 回

実験手順

2-Chloro-3-methylquinoxaline (10.72 g., 0.06 mole) was dissolved in 150 ml. of acetone, treated with Norit and filtered. The filtrate was added to 4.56 g. (0.06 mole) of thiourea in 150 ml. acetone. The solution was stirred at reflux under nitrogen for 2 hours. The precipitate which began to form after 5 minutes, was filtered while the reaction mixture was hot. The solid was collected, washed with hot acetone and dried to give 11.85 g. of a pink solid, m.p. 156°-157° C.

後処理

  1. filtrationfiltered
  2. additionThe filtrate was added to 4.56 g
  3. temperatureat reflux under nitrogen for 2 hours
  4. customto form after 5 minutes
  5. filtrationwas filtered while the reaction mixture
  6. customThe solid was collected
  7. washwashed with hot acetone
  8. customdried
  9. customto give 11.85 g

出典と根拠

ORDレコード
ord-4f4a18a7a7104b0787f29fc49657dc86
出典データセット
uspto-grants-1982_09
特許番号
US04349674

関連ノート

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