Hydrochloric Acid → (4-Decylphenyl)methanol

HRID 1703111ノート

反応式

HRID 1703111 の反応式
B.[CH2:2]([C:12]1[CH:20]=[CH:19][C:15]([C:16](O)=[O:17])=[CH:14][CH:13]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].Cl>O1CCCC1>[CH2:2]([C:12]1[CH:13]=[CH:14][C:15]([CH2:16][OH:17])=[CH:19][CH:20]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

参加物

5

反応物 3

HCID 313Hydrochloric AcidHCID 6331BoraneHCID 123614764-Decylbenzoic acid

生成物 1

HCID 13079698(4-Decylphenyl)methanol

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒2 回

実験手順

To 69.5 ml. of 1 molar borane in tetrahydrofuran chilled in an ice bath is added dropwise over 40 minutes a solution of 17.2 g. of p-decylbenzoic acid in 150 ml. of dry tetrahydrofuran. The mixture is refluxed for 3.5 hours, chilled, 5 ml. of concentrated hydrochloric acid is added and the mixture poured onto ice. The mixture is filtered and the solid washed with water to give white crystals.

後処理

  1. additionis added dropwise over 40 minutes a solution of 17.2 g
  2. temperatureThe mixture is refluxed for 3.5 hours
  3. temperaturechilled
  4. additionthe mixture poured onto ice
  5. filtrationThe mixture is filtered
  6. washthe solid washed with water
  7. customto give white crystals

出典と根拠

ORDレコード
ord-76f58722c44044cf98d0d5129f6d3350
出典データセット
uspto-grants-1982_09
特許番号
US04350822

反応ノート

読み込み中…