2,4-Dichloro-6-methoxy-3,5-triazine → HCID 20337591、化合物

HRID 1706245ノート

反応式

HRID 1706245 の反応式
[CH3:1][O:2][C:3]1[N:8]=[C:7]([Cl:9])[N:6]=[C:5](Cl)[N:4]=1.C([NH:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)=C.[CH:20](N(CC)C(C)C)(C)[CH3:21]>CC(C)=O>[CH3:1][O:2][C:3]1[N:4]=[C:5]([NH:13][C:14]2[CH:15]=[CH:16][C:17]([CH:20]=[CH2:21])=[CH:18][CH:19]=2)[N:6]=[C:7]([Cl:9])[N:8]=1

参加物

5

反応物 3

HCID 192672,4-Dichloro-6-methoxy-3,5-triazineHCID 81531DiisopropylethylamineHCID 6852359N-ethenylaniline

生成物 1

HCID 20337591HCID 20337591、化合物

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

To a solution of 16.4 g (0.1 mole) 2-methoxy-4,6-dichloro-s-triazine in 150 ml of acetone being stirred at 0°-5° C. was added dropwise over a 1/2 hr. period a solution of 11.9 g (0.1 mole) of vinylaniline and 12.9 g (0.1 mole) of N,N-di-iso-propylethylamine. After stirring at room temperature for 2 hr., the solution was poured into 1 l of ice water to isolate the product. The crude product was collected by filtration and dried in vacuo at room temperature to give 24.9 g. Recrystallization was effected by dissolution in 75 ml. of hot benzene followed by addition of ligroin to the cloud point. Yield=20.5 g (78%) (mp 118°-122°).

後処理

  1. additionwas added dropwise over a 1/2 hr
  2. customto isolate the product
  3. filtrationThe crude product was collected by filtration
  4. customdried in vacuo at room temperature
  5. customto give 24.9 g
  6. customRecrystallization
  7. dissolutionwas effected by dissolution in 75 ml
  8. additionof hot benzene followed by addition of ligroin to the cloud point

出典と根拠

ORDレコード
ord-e5d9ff4cbdc94a549591edfe7f3d6678
出典データセット
uspto-grants-1980_06
特許番号
US04206279

反応ノート

読み込み中…