Piperonal → 1-(3,4-Methylenedioxyphenyl)-4-morpholino-1-butene-3-one
反応式
[CH:1]1[C:6]([CH:7]=O)=[CH:5][C:4]2[O:9][CH2:10][O:11][C:3]=2[CH:2]=1.[O:12]1[CH2:17][CH2:16][N:15]([CH2:18][C:19](=[O:21])[CH3:20])[CH2:14][CH2:13]1>[OH-].[Na+]>[CH2:10]1[O:11][C:3]2[CH:2]=[CH:1][C:6]([CH:7]=[CH:20][C:19](=[O:21])[CH2:18][N:15]3[CH2:16][CH2:17][O:12][CH2:13][CH2:14]3)=[CH:5][C:4]=2[O:9]1参加物
4
実験手順
15 g of piperonal (0.1 mole), and 14.3 g of 3-morpholinoacetone (0.1 mole) are mixed in an aqueous-alcoholic sodium hydroxide solution (300 cm3 of 10% NaOH and 30 cm3 of ethanol). The mixture is stirred for 4 hours and the product obtained is then filtered. The product is rinsed with water and recrystallised from ethanol.
後処理
- customthe product obtained
- filtrationis then filtered
- washThe product is rinsed with water
- customrecrystallised from ethanol
出典と根拠
- ORDレコード
- ord-a6230ee247bb4822ab01e7931917fcdd
- 出典データセット
- uspto-grants-1980_06
- 特許番号
- US04209517
反応ノート
読み込み中…