1,1,3-Trichloro-1,2,2,3,3-pentafluoropropane → 1,3-Dichloro-1,1,2,2,3-pentafluoropropane

HRID 1709086

反応式

HRID 1709086 の反応式
[Cl:1][C:2](Cl)([F:10])[C:3]([F:9])([F:8])[C:4]([Cl:7])([F:6])[F:5]>C(O)(C)C>[Cl:7][C:4]([F:6])([F:5])[C:3]([F:9])([F:8])[CH:2]([Cl:1])[F:10]

参加物

3

反応物 1

HCID 742441,1,3-Trichloro-1,2,2,3,3-pentafluoropropane

生成物 1

HCID 623531,3-Dichloro-1,1,2,2,3-pentafluoropropane

試薬・触媒・溶媒 1

HCID 3776Isopropanol溶媒

実験手順

For example, to prepare 1,3-dichloro-1,1,2,2,3-pentafluoropropane, 2,2,3,3-tetrafluoropropanol, tosyl chloride, and water are reacted together to form 2,2,3,3-tetrafluoropropyl p-toluenesulfonate. Then, N-methylpyrrolidone, potassium fluoride, and the 2,2,3,3-tetrafluoropropyl p-toluenesulfonate are reacted together to form 1,1,2,2,3-pentafluoropropane. Then, chlorine and the 1,1,2,2,3-pentafluoropropane are reacted to form 1,1,3-trichloro-1,2,2,3,3-pentafluoropropane. Finally, isopropanol and the 1,1,3-trichloro-1,2,2,3,3-pentafluoropropane are reacted to form 1,3-dichloro-1,1,2,2,3-pentafluoropropane.

出典と根拠

ORDレコード
ord-add53b74b1bb42179fb853d922c7fbad
出典データセット
uspto-grants-1990_08
特許番号
US04947881

関連ノート

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