Dicyclopentadiene → 1-Methyl-2,3,3a,4-tetrahydro-1H-indene

反応式

C1C2C3C=CC(C2C=C1)C3.C12CC(C=C1)C=C2.C=C1CC2CC1C=C2.C(=C1CC2CC1C=C2)C.[C:35](=[C:38]1[CH2:43][CH:42]2[CH2:44][CH:39]1[CH:40]=[CH:41]2)([CH3:37])[CH3:36].C12CC(CC1)C=C2.C1(=C2CC3CC2C=C3)CCCCC1>>[CH3:37][CH:35]1[C:38]2[CH:39]([CH2:40][CH:41]=[CH:42][CH:43]=2)[CH2:44][CH2:36]1

参加物

反応物 7

HCID 6492Dicyclopentadiene

HCID 8473Norbornadiene

HCID 103522-Norbornene

HCID 27756Ethylidenenorbornene

HCID 2603805-Methylenenorbornene

HCID 13908522HCID 13908522、化合物

HCID 14205337HCID 14205337、化合物

生成物 1

HCID 184024371-Methyl-2,3,3a,4-tetrahydro-1H-indene

実験手順

dicyclopentadiene; bicyclo-(2,2,1)-hepta-2,5-diene; alkenyl, alkylidene, cycloalkenyl and cycloalkylidene norbornenes such as 5-methylene -2-norbornene (MNB), 5-ethylidene-2-norbornene (ENB), 5-propylene -2-norbornene, 5-isoproylidene-2-norbornene, 5-(4-cyclopentyenyl) -2-norbornene; 5-cyclohexylidene-2-norbornene.

出典と根拠

ORDレコード: ord-8ccd4008ca72432a8f2c745396fb3f11
出典データセット: uspto-grants-2009_02
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07485603B2

反応ノート

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