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Tin tetrachloride → 4-Isopropoxybenzoyl chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Tin tetrachloride | HCID 24287 | — |
| 反応物 | 2-(Propan-2-yloxy)benzoyl chloride | HCID 15921914 | — |
| 反応物 | CD3OD D2O | HCID 131718569 | — |
| 生成物 | 4-Isopropoxybenzoyl chloride | HCID 2724465 | — |
反応手順
A sample vial was filled with 2 g of isopropoxy benzoyl chloride and SnCl4 was injected. The mixture was homogenized and then kept at the reaction temperature chosen. After the reaction 50 mg of the solidified red-brown reaction mixture was hydrolyzed in 1 ml of a mixture of CD3OD/D2O/NaOD (12:3:1, weight ratios) (2 hours, 60° C.) and the degree of polymerization (dp) was determined by NMR end-group analysis.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05332858 |
| 出典データセット | uspto-grants-1994_07 |
| ORD ID | ord-98079c3b60b94ac4b64872f79ce599ea |
| 出典メモ | uspto-grants-1994_07 |