1-Bromodecane → Decyl thiocyanate

HRID 1730382

反応式

HRID 1730382 の反応式
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[S-:12][C:13]#[N:14].[Na+].[Cl-].C(C([NH3+])(C(=O)CCCCCCC)C(=O)CCCCCCC)(=O)CCCCCCC>O>[S:12]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[C:13]#[N:14]

参加物

5

反応物 3

HCID 81731-BromodecaneHCID 516871Sodium thiocyanateHCID 77620884Tricaprylylmethyl ammonium chloride

生成物 1

HCID 79301Decyl thiocyanate

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A mixture of 100 grams (0.45 mole) of 1-bromodecane, 160 grams (1.98 moles)of sodium thiocyanate, 50 ml water and 10 grams of tricaprylylmethylammonium chloride was heated to 88°-105° C with stirring over a period of 2 hours. Examination of the reaction mixture by gas liquid partition chromatography showed that 100% conversionof the 1-bromodecane had occurred to give 1-thiocyanodecane.

後処理

  1. temperaturewas heated to 88°-105° C
  2. customExamination of the reaction mixture by gas liquid partition chromatography

出典と根拠

ORDレコード
ord-40daf765ff7f42f69c9e152c4d0c32ab
出典データセット
uspto-grants-1976_11
特許番号
US03992432

関連ノート

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