4-Chlorobenzaldehyde → HCID 178504058、化合物

反応式

Br[C:2]1[CH:14]=[CH:13][C:5]([CH:6]=[N:7][NH:8][C:9](=[NH:12])[S:10][CH3:11])=[CH:4][CH:3]=1.[Cl:15]C1C=CC(C=O)=CC=1.C(=N)(SC)NN.I.C(C1C=CC(C=NNC(=N)SCC)=CC=1)#N.C(C1C=CC(C=O)=CC=1)#N.I.C(=N)(SCC)NN.Br.ClC1C=C(C=CC=1Cl)C=NNC(=N)SCCC.ClC1C=C(C=CC=1Cl)C=O.Br.C(=N)(SCCC)NN>>[ClH:15].[Cl:15][C:2]1[CH:14]=[CH:13][C:5]([CH:6]=[N:7][NH:8][C:9](=[NH:12])[S:10][CH3:11])=[CH:4][CH:3]=1

参加物

反応物 9

HCID 77264-Chlorobenzaldehyde

HCID 227103,4-Dichlorobenzaldehyde

HCID 660424-Cyanobenzaldehyde

HCID 178419558HCID 178419558、化合物

HCID 178419559HCID 178419559、化合物

HCID 178477488HCID 178477488、化合物

HCID 178477489HCID 178477489、化合物

HCID 178504051Methyl hydrazinecarbimidothioate

HCID 178504057HCID 178504057、化合物

生成物 1

HCID 178504058HCID 178504058、化合物

実験手順

The following are prepared in like manner: methyl 3-(4-bromobenzylidene)thiocarbazimidate methosulfate from 4-chlorobenzaldehyde and methyl thiocarbazimidate methosulfate, ethyl 3-(4-cyanobenzylidene)thiocarbazimidate hydroiodide from 4-cyanobenzaldehyde and ethyl thiocarbazimidate hydroiodide, and propyl 3-(3,4-dichlorobenzylidene)thiocarbazimidate hydrobromide from 3,4-dichlorobenzaldehyde and propyl thiocarbazimidate hydrobromide.

後処理

customThe following are prepared in like manner

出典と根拠

ORDレコード: ord-de8e5c08fd3b42efa4e4a01f2d06e745
出典データセット: uspto-grants-1976_11
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US03992446

反応ノート

読み込み中…