Methane → 4,5-Dihydroxy-2-nitrobenzeneacetonitrile
反応式
C.[N+:2]([C:5]1[CH:10]=[C:9]([O:11]CC2C=CC=CC=2)[C:8]([O:19]CC2C=CC=CC=2)=[CH:7][C:6]=1[CH2:27][C:28]#[N:29])([O-:4])=[O:3].C1CCCCC=1>[Pd].C(O)C>[N+:2]([C:5]1[CH:10]=[C:9]([OH:11])[C:8]([OH:19])=[CH:7][C:6]=1[CH2:27][C:28]#[N:29])([O-:4])=[O:3]参加物
6
実験手順
0.75 g of palladium at a concentration of 10% on charcoal, to which 3 g of charcoal have been added, followed by 0.02 mole (7.5 g) of 2-nitro-4,5-dibenzyloxyphenylacetonitrile, are added with stirring to 30 ml of 96° C. ethanol containing 15 ml of cyclohexene; the reaction mixture is heated under reflux for 1 hour.
後処理
- additionare added
- temperaturethe reaction mixture is heated
- temperatureunder reflux for 1 hour
出典と根拠
- ORDレコード
- ord-9756170153af4b40b5bfee2da79789b0
- 出典データセット
- uspto-grants-1996_07
- 特許番号
- US05536865
反応ノート
読み込み中…