Sulfuric Acid → 1,3-Bis(2-t-amylperoxy-2-propyl)benzene

HRID 1735917

反応式

HRID 1735917 の反応式
[C:1]([O:6][OH:7])([CH2:4][CH3:5])([CH3:3])[CH3:2].OC([C:12]1[CH:17]=[CH:16][C:15]([C:18]([OH:21])([CH3:20])[CH3:19])=[CH:14][CH:13]=1)(C)C.S(=O)(=O)(O)O>O>[C:1]([O:6][O:7][C:12]([C:13]1[CH:12]=[CH:17][CH:16]=[C:15]([C:18]([O:21][O:21][C:18]([CH2:15][CH3:14])([CH3:20])[CH3:19])([CH3:19])[CH3:20])[CH:14]=1)([CH3:17])[CH3:13])([CH2:4][CH3:5])([CH3:3])[CH3:2]

参加物

5

反応物 3

HCID 1118Sulfuric AcidHCID 18062p-Bis(2-hydroxyisopropyl)benzeneHCID 76962tert-Amyl hydroperoxide

生成物 1

HCID 541315831,3-Bis(2-t-amylperoxy-2-propyl)benzene

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

1,4-Bis(2-t-amylperoxy-2-propyl)benzene (para III) was prepared by reacting 28.1 grams (0.231 mole) of aqueous 85.7% t-amyl hydroperoxide diluted with 3.2 grams of water with 20.4 grams (0.105 mole) of 1,4-bis(2-hydroxy-2-propyl)benzene in the presence of 44.1 grams (0.316 mole) of 70% sulfuric acid according to the procedure of Example VII. The stripped product was a yellow liquid which remained liquid at 15° C. The product weighed 32.0 grams.

後処理

  1. customat 15° C

出典と根拠

ORDレコード
ord-4a4d45c4eb9243e2a9facd98ed10c5f3
出典データセット
uspto-grants-1996_07
特許番号
US05539061

関連ノート

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