Perchloric Acid → 2-(2-Chlorophenyl)propanal
反応式
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]([CH3:12])=[CH:9][O:10]C.Cl(O)(=O)(=O)=O>CCOCC>[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH:8]([CH3:12])[CH:9]=[O:10]参加物
4
実験手順
To a solution of 2-(2-chlorophenyl)-1-methoxypropene (712 mg, 3.9 mmol) in ether (8 ml) at 0° C. was added perchloric acid (70%, 3 ml). After stirring for 1 h the solution was diluted with ether (8 ml) and washed with water (2×20 ml). The organic phase was separated, dried (Na2SO4) and evaporated. The crude 2-(2-chlorophenyl)propanal was isolated as a colourless oil and used without further purification.
後処理
- washwashed with water (2×20 ml)
- customThe organic phase was separated
- dry with materialdried (Na2SO4)
- customevaporated
出典と根拠
- ORDレコード
- ord-5010c68538e043bc9e36acd23bfe54e7
- 出典データセット
- uspto-grants-1999_10
- 特許番号
- US05973156
反応ノート
読み込み中…