2-Fluoroethyl bromide → HCID 22234989、化合物
反応式
[N+:1]([C:4]1[CH:15]=[CH:14][C:7]([CH2:8][CH:9]([C:12]#[N:13])[C:10]#[N:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].[H-].[Na+].Br[CH2:19][CH2:20][F:21]>CN(C)C=O>[N+:1]([C:4]1[CH:5]=[CH:6][C:7]([CH2:8][C:9]([CH2:19][CH2:20][F:21])([C:10]#[N:11])[C:12]#[N:13])=[CH:14][CH:15]=1)([O-:3])=[O:2]参加物
5
実験手順
Using 0.40 g of (4-nitrobenzyl)malononitrile, 5 ml of N,N-dimethylformamide, 0.12 g of sodium hydride (60% in oil), and 0.25 g of 1-bromo-2-fluoroethane, and according to the process described in the Production Example 1, there was obtained 0.10 g of 2-(4-nitrobenzyl)-2-(2-fluoroethyl)malononitrile (the present compound (47)).
出典と根拠
- ORDレコード
- ord-49ae51033f73415faf9bf418aeb8c460
- 出典データセット
- uspto-grants-2006_03
- 特許番号
- US07011838B2
反応ノート
読み込み中…