Oxalyl chloride → 3-(Naphthalen-1-yl)prop-2-enoyl chloride

反応式

[C:1]1([CH:11]=[CH:12][C:13]([OH:15])=O)[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1.C(Cl)(=O)C([Cl:19])=O>>[C:1]1([CH:11]=[CH:12][C:13]([Cl:19])=[O:15])[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1

参加物

反応物 2

HCID 65578Oxalyl chloride

HCID 983073-(1-Naphthalenyl)-2-propenoic acid

生成物 1

HCID 534112803-(Naphthalen-1-yl)prop-2-enoyl chloride収率 99%

実験手順

3-(1-Naphthalenyl)-2-Propenoic acid (7.5 g, 0.038 mol) was slurried in 15 ml of oxalyl chloride and refluxed for 2 hr. The resulting solution was evaporated to yield 8.0 g (99 percent) of yellow solid.

後処理

temperaturerefluxed for 2 hr
customThe resulting solution was evaporated

出典と根拠

ORDレコード: ord-10a1d8b48b314b528ebc2caf84467651
出典データセット: uspto-grants-2006_03
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07012121B2

反応ノート

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