Triethylamine → HCID 117761061、化合物

反応式

Br[CH2:2][C:3]1[CH:8]=[C:7]([Br:9])[CH:6]=[C:5]([Br:10])[C:4]=1[OH:11].N[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[SH:19].C([N:22](CC)CC)C>C1COCC1>[NH2:22][S:19][C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][C:13]=1[CH2:2][C:3]1[CH:8]=[C:7]([Br:9])[CH:6]=[C:5]([Br:10])[C:4]=1[OH:11]

参加物

実験手順

A solution of 2-(bromomethyl)-4,6-dibromophenol (1.48 g, 4.3 mmol) in THF (20 mL) was added dropwise to a solution of 2-Aminothiophenol (0.54 g, 4.3 mmol) and triethylamine (0.60 mL) in THF (20 mL) and stirred at room temperature for 12 hours. A solid had formed and was filtered out followed by removal of the solvent in vacuum. The crude product was dissolved in dichloromethane, washed with saturated NaCl solution and dried over MgSO4. The product was obtained as a yellow oil in a quantitative yield.