Hydrazine → Copper oxalate hydrazine

反応式

[C:1]([O-:6])(=[O:5])[C:2]([O-:4])=[O:3].[Cu+2:7].O.[NH2:9][NH2:10].NN>>[C:1]([O-:6])(=[O:5])[C:2]([O-:4])=[O:3].[Cu+2:7].[NH2:9][NH2:10]

参加物

反応物 3

HCID 9321Hydrazine

HCID 13148Copper(II) oxalate2 回

HCID 24654Hydrazine hydrate (1:1)

生成物 1

HCID 86696623Copper oxalate hydrazine

実験手順

A bluish white powder of copper oxalate was mixed with an excessive amount of hydrazine monohydrate (liquid) and the mixture stirred at room temperature, by which both the compounds formed a complex. By so doing, a purple copper oxalate-hydrazine complex (composite compound) was obtained. The composite compound was thought to be a complex formed as a result of coordinate-bonding through unshared electron pairs of nitrogen which constituted hydrazine to copper atoms contained in the copper oxalate.