1-[4-(3-Carbomethoxyprop-2-eneoxy)phenyl]propan-2-one → 1-(4-[3-Carbomethoxypropoxy]phenyl)propan-2-one

HRID 1758988ノート

反応式

HRID 1758988 の反応式
[C:1]([CH:5]=[CH:6][CH2:7][O:8][C:9]1[CH:14]=[CH:13][C:12]([CH2:15][C:16](=[O:18])[CH3:17])=[CH:11][CH:10]=1)([O:3][CH3:4])=[O:2].[H][H]>C(O)C.[Pd]>[C:1]([CH2:5][CH2:6][CH2:7][O:8][C:9]1[CH:10]=[CH:11][C:12]([CH2:15][C:16](=[O:18])[CH3:17])=[CH:13][CH:14]=1)([O:3][CH3:4])=[O:2]

参加物

5

反応物 2

HCID 538253751-[4-(3-Carbomethoxyprop-2-eneoxy)phenyl]propan-2-oneHCID 178418361HCID 178418361、化合物

生成物 1

HCID 130796131-(4-[3-Carbomethoxypropoxy]phenyl)propan-2-one収率 99.2%

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 702Ethanol溶媒

実験手順

To a solution of 1-[4-(3-carbomethoxyprop-2-eneoxy)phenyl]propan-2-one (1.1 g) in ethanol (50 ml), was added 10% Pd/C (100 mg) and the mixture hydrogenated at ambient temperature and atmospheric pressure until hydrogen uptake was complete (approx. 10 minutes). The solution was filtered, evaporated to give the title compound (1.1 g) as an oil.

後処理

  1. customhydrogenated at ambient temperature
  2. custom(approx. 10 minutes)
  3. filtrationThe solution was filtered
  4. customevaporated

出典と根拠

ORDレコード
ord-5fe1d94af7b0417cb1bc3a573dc4aeb7
出典データセット
uspto-grants-1982_07
特許番号
US04338333

反応ノート

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