HCID 21349241、化合物 → HCID 53746442、化合物
反応式
[CH3:1][C:2]1([OH:13])[CH2:11][CH2:10][CH2:9][CH:8]2[CH:3]1[CH:4]1[CH2:12][CH:7]2[CH:6]=[CH:5]1>CO.[Pd]>[CH3:1][C:2]1([OH:13])[CH2:11][CH2:10][CH2:9][CH:8]2[CH:3]1[CH:4]1[CH2:12][CH:7]2[CH2:6][CH2:5]1参加物
4
実験手順
25 g (0.140 mole) of 3-methyl-tricyclo[6.2.1.02,7 ]undec-9-en-3-ol--see Example 1--in 150 ml of methanol were hydrogenated under atmospheric pressure and at room temperature in the presence of 2.5 g of 10% palladium on charcoal. After filtration, evaporation and distillation (b.p. 60°-65°/0.1 Torr), 24 g of a material containing ca. 90% of the desired compound according to vapor phase chromatographic analysis were isolated.
後処理
- filtrationAfter filtration, evaporation and distillation (b.p. 60°-65°/0.1 Torr), 24 g of a material
- additioncontaining ca. 90% of the desired compound
- customwere isolated
出典と根拠
- ORDレコード
- ord-61218d801649411a9043570d6425f2bb
- 出典データセット
- uspto-grants-1982_07
- 特許番号
- US04341666
反応ノート
読み込み中…