(3-Phenoxy-phenyl)-2-propyn-1-yl alcohol → 2,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid

HRID 1762607ノート

反応式

HRID 1762607 の反応式
[CH3:1][C:2]1([CH3:16])[CH:4]([CH:5]=[CH:6][C:7]([O:9][CH2:10][CH2:11][CH3:12])=[O:8])[CH:3]1[C:13]([OH:15])=[O:14].O(C1C=C(C#CCO)C=CC=1)C1C=CC=CC=1>C(Cl)(Cl)Cl>[CH3:16][C:2]1([CH3:1])[CH:4]([CH:5]=[CH:6][C:7]([O:9][CH2:10][CH2:11][CH3:12])=[O:8])[CH:3]1[C:13]([OH:15])=[O:14].[CH3:16][C:2]1([CH3:1])[CH:4]([CH:5]=[CH:6][C:7]([O:9][CH2:10][CH2:11][CH3:12])=[O:8])[CH:3]1[C:13]([O-:15])=[O:14]

参加物

5

反応物 2

HCID 53853920(3-Phenoxy-phenyl)-2-propyn-1-yl alcoholHCID 545705842,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid2 回

生成物 2

HCID 545705842,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acidHCID 736552732,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylate

試薬・触媒・溶媒 1

HCID 6212Chloroform溶媒

実験手順

Using the procedure of Example 9, (1R, cis, ΔZ) 2,2-dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid and 1R (3-phenoxy-phenyl)-2-propyn-1-yl alcohol were reacted to obtain 1R (3-phenoxy-phenyl)-2-propyn-1-yl (1R, cis, ΔZ) 2,2-dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylate with a specific roation of [α]D20 =+48°±2° (c=1% in chloroform).

後処理

  1. customwere reacted

出典と根拠

ORDレコード
ord-dfd29c4a7898454f80fc2cf4d64f1736
出典データセット
uspto-grants-1989_05
特許番号
US04833163

反応ノート

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