関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | tert-Butyl mercaptan | HCID 6387 | — |
| 反応物 | 1,3,5-Trimethyl-1,3,5-triazacyclohexane | HCID 7952 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | N-(tert.-butylthiomethyl)-N-methyl amine hydrochloride | HCID 20309108 | — |
反応手順
Two hundred ml. of acetonitrile and 6.45 g. (0.05 mole) of 1,3,5-trimethylhexahydro-s-triazine are charged to a 500 ml. 3-neck round bottom flask equipped with a stirrer, thermometer and dropping funnel. The mixture is stirred and cooled to -30° C. with a dry ice/acetone bath. Six grams of hydrogen chloride gas are added, followed by slow addition of 13.5 g. (0.15 mole) of tert.-butyl mercaptan dissolved in 50 ml. of acetonitrile. The mixture is then allowed to warm to room temperature and stand overnight.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04111682 |
|---|
| 出典データセット | uspto-grants-1978_09 |
|---|
| ORD ID | ord-5246002422484162be2eb192c1c5b48a |
|---|
| 出典メモ | uspto-grants-1978_09 |
|---|
