Hydrochloric Acid → HCID 20309108, compound

HRID 1763186Notes

Reaction equation

HRID 1763186 reaction equation
[CH3:1][N:2]1[CH2:7]N(C)CN(C)C1.[ClH:10].[C:11]([SH:15])([CH3:14])([CH3:13])[CH3:12]>C(#N)C>[ClH:10].[C:11]([S:15][CH2:7][NH:2][CH3:1])([CH3:14])([CH3:13])[CH3:12]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 6387tert-Butyl mercaptanHCID 79521,3,5-Trimethyl-1,3,5-triazacyclohexane

Product 1

HCID 20309108HCID 20309108, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent2×

Conditions

Temperature
-30 °C

Procedure

Two hundred ml. of acetonitrile and 6.45 g. (0.05 mole) of 1,3,5-trimethylhexahydro-s-triazine are charged to a 500 ml. 3-neck round bottom flask equipped with a stirrer, thermometer and dropping funnel. The mixture is stirred and cooled to -30° C. with a dry ice/acetone bath. Six grams of hydrogen chloride gas are added, followed by slow addition of 13.5 g. (0.15 mole) of tert.-butyl mercaptan dissolved in 50 ml. of acetonitrile. The mixture is then allowed to warm to room temperature and stand overnight.

Workup

  1. custom3-neck round bottom flask equipped with a stirrer
  2. additionfollowed by slow addition of 13.5 g
  3. temperatureto warm to room temperature

Sources & evidence

ORD record
ord-5246002422484162be2eb192c1c5b48a
Source dataset
uspto-grants-1978_09
Patent number
US04111682

Reaction notes

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