Dichloromethane → HCID 13363448、化合物

反応式

[CH3:1][N:2]([S:6]Cl)[C:3]([Cl:5])=[O:4].[CH2:8]([Cl:12])[C:9](=[CH2:11])[CH3:10].C(Cl)[Cl:14]>>[CH3:1][N:2]([S:6][C:9]([CH3:10])([CH2:11][Cl:14])[CH2:8][Cl:12])[C:3]([Cl:5])=[O:4]

参加物

反応物 3

HCID 6344Dichloromethane

HCID 112413-Chloro-2-methyl-1-propene

HCID 20437446HCID 20437446、化合物

生成物 1

HCID 13363448HCID 13363448、化合物

実験手順

To a solution of 16.0g of N-methyl-N-chlorosulfenyl carbamoyl chloride in 100 ml of methylene chloride was added 12.0g of methallyl chloride with stirring, at room temperature. On slight heating there was a spontaneous exotherm which raised the temperature of the reaction mixture to 39° C. On removal of the solvent under reduced pressure 19.6g of oil was obtained. nD25 1.5379. Infra-red (neat) 5.76 (C=O), 8.0, 8.65, 9.8, 11.8, 12.25, 13.45 and 14.0μ. NMR(CDCl3) δ 1.41 (s), 3H; 3.48 (s), 3H; 3.87 (d). JAB = 12.0 HZ and 3.97 (d), JBA = 12.0 HZ 4H. Calc'd. for C6H10Cl3NOS: C, 28.76; H, 4.02; N, 5.59. Found: C, 28.87; H, 3.87; N, 4.72.