Bromine → 5-Bromo-2-isocyanato-1,3-di(propan-2-yl)benzene
反応式
[CH:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH:10]([CH3:12])[CH3:11])[C:5]=1[N:13]=[C:14]=[O:15])([CH3:3])[CH3:2].[Br:16]Br.S([O-])([O-])(=O)=O.[Na+].[Na+]>[Fe]>[CH:1]([C:4]1[CH:9]=[C:8]([Br:16])[CH:7]=[C:6]([CH:10]([CH3:11])[CH3:12])[C:5]=1[N:13]=[C:14]=[O:15])([CH3:2])[CH3:3]参加物
5
反応条件
- 温度
- 120 °C
実験手順
0.5 g of anhydrous iron-III chloride is added to 203 g of 2,6-diisopropyl-phenyl isocyanate and 162 g of bromine are added dropwise at 20° C. The mixture is then slowly warmed to 120° C until the evolution of gas has ceased. 3.0 g of anhydrous sodium sulfate are then added and the mixture is fractionated in vacuo.
後処理
- additionare added dropwise at 20° C
出典と根拠
- ORDレコード
- ord-602193caef084564a7466dbbd3d51425
- 出典データセット
- uspto-grants-1978_09
- 特許番号
- US04112065
反応ノート
読み込み中…