Trifluoroacetic acid → HCID 18947042、化合物

HRID 1769090ノート

反応式

HRID 1769090 の反応式
[CH3:1][CH:2]([C:4]1[S:5][CH:6]=[C:7]2[CH2:11][N:10](C(OC(C)(C)C)=O)[CH2:9][C:8]=12)[CH3:3].[F:19][C:20]([F:25])([F:24])[C:21]([OH:23])=[O:22]>>[F:19][C:20]([F:25])([F:24])[C:21]([OH:23])=[O:22].[CH3:3][CH:2]([C:4]1[S:5][CH:6]=[C:7]2[CH2:11][NH:10][CH2:9][C:8]=12)[CH3:1]

参加物

3

反応物 2

HCID 6422Trifluoroacetic acidHCID 189470581-(1-Methylethyl)-5-(1,1-dimethylethoxy)carbonyl-5,6-dihydro-4H-thieno[3,4-c]pyrrole

生成物 1

HCID 18947042HCID 18947042、化合物

実験手順

A solution of 0.49 g (1.8 mmol) of 1-(1-methylethyl)5-(1,1-dimethylethoxy)carbonyl-5,6-dihydro -4H-thieno[3,4-c]pyrrole in 0.5 ml of trifluoroacetic acid is stirred for 30 min at a temperature in the region of 20° C. After evaporation of the solvent, 0.51 g of an oily product is obtained. Quantitative yield.

後処理

  1. customAfter evaporation of the solvent

出典と根拠

ORDレコード
ord-53f02e5540364c7a80628e67b63888f6
出典データセット
uspto-grants-1995_01
特許番号
US05380742

反応ノート

読み込み中…