4-Benzeneazodiphenylamine → Aniline

HRID 1769845

反応式

HRID 1769845 の反応式
[CH:1]1[CH:6]=[CH:5][C:4]([NH:7][C:8]2[CH:13]=[CH:12][C:11]([N:14]=NC3C=CC=CC=3)=[CH:10][CH:9]=2)=[CH:3][CH:2]=1.C1(O)CCCCC1.CC(C)([O-])C.[K+]>>[CH:1]1[CH:2]=[CH:3][C:4]([NH:7][C:8]2[CH:13]=[CH:12][C:11]([NH2:14])=[CH:10][CH:9]=2)=[CH:5][CH:6]=1.[NH2:7][C:4]1[CH:5]=[CH:6][CH:1]=[CH:2][CH:3]=1

参加物

5

反応物 3

HCID 75754-BenzeneazodiphenylamineHCID 7966CyclohexanolHCID 23665647Potassium tert-butoxide

生成物 2

HCID 6115AnilineHCID 7564N-Phenyl-p-phenylenediamine

実験手順

A solution of 4-(phenylazo)diphenylamine (0.273 g), cyclohexanol (5 g) and potassium t-butoxide (1 g) was heated at reflux under nitrogen for 4 hours. Analysis of the reaction mixture by HPLC indicated all of the 4-(phenyazo)-diphenylamine was consumed. 4-aminodiphenylamine and aniline were produced in 99% yield based on 4-(phenylazo)diphenylamine charged.

後処理

  1. temperatureat reflux under nitrogen for 4 hours
  2. customwas consumed

出典と根拠

ORDレコード
ord-c8e6b65f71374bab982a36394e8cf5ba
出典データセット
uspto-grants-1995_01
特許番号
US05382691

関連ノート

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