1-Hexene → 4,4-Dichloro-2-phenyl-4-siladecane

HRID 1770329ノート

反応式

HRID 1770329 の反応式
[C:1]1([CH:7]([CH3:12])[CH2:8][SiH:9]([Cl:11])[Cl:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:13]=[CH:14][CH2:15][CH2:16][CH2:17][CH3:18]>C(O)(C)C.[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[Cl:10][Si:9]([Cl:11])([CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH2:8][CH:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH3:12]

参加物

5

反応物 2

HCID 115971-HexeneHCID 1233243423-Phenyl-1,1-dichloro-1-silabutane

生成物 1

HCID 218414464,4-Dichloro-2-phenyl-4-siladecane収率 60.6%

試薬・触媒・溶媒 2

HCID 61859Chloroplatinic acid触媒HCID 3776Isopropanol溶媒

実験手順

in the same apparatus and procedures as EXAMPLE 1, 5.0 g (0.023 mole) of 3-phenyl-1,1-dichloro-1-silabutane, 5.8 g (0.07 mole) of 1-hexene, and 100 μl of 1% chloroplatinic acid in isopropanol were placed and reacted under the dry nitrogen atmosphere. Vacuum distillation of the reaction products gave 4.23 g (bp, 115°-8° C./0.6 mmHg) of 4,4-dichloro-2-phenyl-4-siladecane.

後処理

  1. customreacted under the dry nitrogen atmosphere
  2. distillationVacuum distillation of the reaction products

出典と根拠

ORDレコード
ord-f3bde85830fd459c8dc633004235f479
出典データセット
uspto-grants-1995_01
特許番号
US05386050

反応ノート

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