2,6-Dinitrophenyl methyl ether → 1,3-Benzenediamine, 2-methoxy-

HRID 1773497

反応式

HRID 1773497 の反応式
[CH3:1][O:2][C:3]1[C:8]([N+:9]([O-])=O)=[CH:7][CH:6]=[CH:5][C:4]=1[N+:12]([O-])=O>[Pd].C(O)C>[CH3:1][O:2][C:3]1[C:8]([NH2:9])=[CH:7][CH:6]=[CH:5][C:4]=1[NH2:12]

参加物

4

反応物 1

HCID 5977192,6-Dinitrophenyl methyl ether

生成物 1

HCID 124029761,3-Benzenediamine, 2-methoxy-収率 105.9%

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 702Ethanol溶媒

実験手順

A mixture of 2-methoxy-1,3-dinitro-benzene (1.49 g) and palladium on carbon (10%, 150 mg) in ethanol (75 mL) was stirred under hydrogen atmosphere (1 atm.) overnight. The catalyst was filtered off on a CELITE™ pad and the filter cake was washed with ethanol. The filtrate was evaporated under reduced pressure to afford 1.1 g of 2-methoxy-benzene-1,3-diamine as a light yellow solid without further purifications.

後処理

  1. filtrationThe catalyst was filtered off on a CELITE™ pad
  2. washthe filter cake was washed with ethanol
  3. customThe filtrate was evaporated under reduced pressure

出典と根拠

ORDレコード
ord-b6106108b7c0418e8d29c9345847431d
出典データセット
uspto-grants-2016_02
特許番号
US09255110B2

関連ノート

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