Tetrahydrofuran → (1RS,4RS)-4-hydroxy-4-(3-trimethylsilyl-2-propynyl)-2-cyclopenten-1-yl (t-butyldimethylsilyl) ether

HRID 177829

反応式

[C:13]([CH3:14])([CH3:15])([CH3:16])[Si:17]([CH3:18])([CH3:19])[O:20][CH:21]1[CH:22]=[CH:23][C:24](=[O:26])[CH2:25]1.[CH2:8]([Li:9])[CH2:10][CH2:11][CH3:12].[CH3:1][Si:2]([CH3:3])([CH3:4])[C:5]#[C:6][CH3:7].[CH3:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37].[O:27]1[CH2:28][CH2:29][CH2:30][CH2:31]1>>[CH3:1][Si:2]([CH3:3])([CH3:4])[C:5]#[C:6][CH2:7][C:24]1([OH:26])[CH:23]=[CH:22][CH:21]([O:20][Si:17]([C:13]([CH3:14])([CH3:15])[CH3:16])([CH3:18])[CH3:19])[CH2:25]1