Ethyl 3-ethoxycarbonyloxy-1,4-dihydro-1,4-dioxo-2-naphthoate → HCID 178470044、化合物
反応式
C(OC([O:6][C:7]1[C:16](=[O:17])[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[C:9](=[O:18])[C:8]=1[C:19]([O:21][CH2:22][CH3:23])=[O:20])=O)C>O1CCCC1>[OH:6][C:7]1[C:16](=[O:17])[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[C:9](=[O:18])[C:8]=1[C:19]([O:21][CH2:22][CH3:23])=[O:20]参加物
3
実験手順
To the tetrahydrofuran solution under water cooling was added a solution of ethyl 3-ethoxycarbonyloxy-1,4-dihydro-1,4-dioxo-2-naphthoate, obtained by the procedure of Referential Example 22(1) using 3.41 g of ethyl 3-hydroxy-1,4-dihydro-1,4-dioxo-2-naphthoate, in 10 ml of tetrahydrofuran. The mixture was stirred at room temperature for 2 hours. The reaction solution was poured into 100 ml of ethanol, and the resulting crystals were collected by filtration and recrystallized from chloroform - ethanol to give the title compound, m.p. 224°-227° C., yield of 3.70 g.
出典と根拠
- ORDレコード