HCID 602709、化合物 → HCID 22039032、化合物
反応式
[CH2:1]([O:3][C:4]1[CH:5]=[C:6]([CH2:12][OH:13])[CH:7]=[C:8]([CH2:10][OH:11])[CH:9]=1)[CH3:2]>C(Cl)Cl.O=[Mn]=O>[CH2:1]([O:3][C:4]1[CH:5]=[C:6]([CH:7]=[C:8]([CH2:10][OH:11])[CH:9]=1)[CH:12]=[O:13])[CH3:2]参加物
4
実験手順
MnO2 (8.37 g, 96.3 mmol) was added to a solution of (3-ethoxy-5-hydroxymethyl-phenyl)-methanol (17.55 g, 96.3 mmol) in CH2Cl2 (175 ml) and the mixture was stirred for 64 h. at room temperature. Thereafter, further MnO2 (8.37 g, 96.3 mmol) was added and the mixture was stirred for 6 h. The mixture was-filtered over Celite and the filtrate was concentrated. The product was purified by chromatography. There were obtained 8.32 g (48%) of 3-ethoxy-5-hydroxymethyl-benzaldehyde as a colorless oil.
後処理
- stirringthe mixture was stirred for 6 h
- filtrationThe mixture was-filtered over Celite
- concentrationthe filtrate was concentrated
- customThe product was purified by chromatography
出典と根拠
- ORDレコード
- ord-b4b87759f5b84d4eb1f867937d51c9e7
- 出典データセット
- uspto-grants-2006_07
- 特許番号
- US07071212B2
反応ノート
読み込み中…